Advances in Heterocyclic Chemistry Volume 59 by Alan R. Katritzky

By Alan R. Katritzky

Verified in 1960, Advances in Heterocyclic Chemistry is the definitive serial within the area-one of serious significance to natural chemists, polymer chemists, and such a lot organic scientists. each 5th quantity ofAdvances in Heterocyclic Chemistry encompasses a cumulative topic index.

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SILVESTER [Sec. B nucleophilic aromatic substitution [87JCS(P1)2119; 88JCS(Pl)l179]. A variation in reactant ratios enables 1 : 1,2 : 1, and 3 : 1 adducts to be readily obtained with tetrafluoropyridazine. Substitution with pentafluoropyridine occurs at the 4 position, with further attack being determined by thermodynamic and kinetic control reminiscent of perfluoroalkylation reactions with carbanions. Until recently the substitution pattern in pentafluoropyridine was considered to be 4 + 2; however, several examples have been found where substitution at the 2 position occurs to a greater extent than expected, for example, with sodium oximate.

Thiadiazolo(x,y-z][ I ,3-,4]triazines . . . . . . . . . . . . . . . . . 1 . 4jtriazines. . . . . . . . . . . . 2. 3,4]Thiadiazolo[3. 3 . 4]triazines. . . . . . . . . . . . XIII. 4]triazines . . 4]t riazi ................... I . 4]triazines . . . . . . . . . . . . . . . 2. 2,4]triazines . . . . 3. 2,4]triazines . . . . . . . . . . . . . . . ................... 4. 2,4]triazines . . . Appendix .

S. Chem. Commirn.. 1699 (1987). V. A. Ponomarenko, T. N . Redina, A. A. Yarosh, A. A. Zharov, V. M . Zhulin, and A. V. Ignatenko, f z u . Akatl. Nard SSSR, Ser. Khim.. 1893 (1987) [CA 109, 37799 (1988)l. S. Rozen, D. Hebel, and D. Zamir, J. Am. Chem. Soc. 109,3789 (1987). S. Singh. D. D. DesMarteau. S. S. Zuberi. M. -N. Huang, J . Am. Chem. Soc. 109, 7194 (1987). A. E. Bayliff, M. R. Bryce, and R. D. S. Perkin I. 763 (1987). G . M . Brooke and J . A. K. J. S. Perkin I . 2091 (1987). W. Dmowski and A.

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