Advances in Enzymology and Related Areas of Molecular by Alton Meister

By Alton Meister

Advances in Enzymology and comparable components of Molecular Biology is a seminal sequence within the box of biochemistry, providing researchers entry to authoritative reports of the newest discoveries in all components of enzymology and molecular biology. those landmark volumes date again to 1941, offering an unequalled view of the ancient improvement of enzymology. The sequence bargains researchers the newest knowing of enzymes, their mechanisms, reactions and evolution, roles in complicated organic technique, and their program in either the laboratory and undefined. every one quantity within the sequence gains contributions by way of top pioneers and investigators within the box from world wide. All articles are rigorously edited to make sure thoroughness, caliber, and clarity.

With its wide selection of themes and lengthy ancient pedigree, Advances in Enzymology and comparable components of Molecular Biology can be utilized not just by way of scholars and researchers in molecular biology, biochemistry, and enzymology, but in addition by means of any scientist drawn to the invention of an enzyme, its homes, and its applications.

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Additional info for Advances in Enzymology and Related Areas of Molecular Biology, Volume 11 (v. 11)

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And Murphy, G. , Mathematics of Physics and Chemistry. Van Nostrand, New York, 1943. 6. ,Statistical Mechanics. University Press, Oxford, 1949. 7. , Etude therniodynamique des phdnomhnes irreversibles. Desoer, LiBge, 1947. 8. Denbigh, K. , and Page, F. , Trans. ,44, 479 (1948). 9. , J . Mt. Sinai Hospital, 14, 891 (1948). 10. Butler, J. A. , Nature, 158, 153 (1946). 11. Reiner, J. , J . Phys. , 49, 81 (1945). 12. Bridgman, P. , The Nature of ‘I’hermodynamics. Harvard Univ. , 1941, p. 133. 13.

SIGNIFICANCE FOR STUDIES WITH ENZYMES The concentration of thiol groups a t an interface may be important in enzyme studies for a variety of reasons: (i) the enzyme reaction may involve a thiol directly; (ii) the reaction may involve a thiol as coenzyme or cosubstrate; (iii) the enzyme may itself be a n SH protein, and active to greater or lesser degrees in the oxidized and reduced states; (iv) the enzyme, while not an SH protein, may be subject t o oxidation or reduction by SH:SS systems, and thus have its activity influenced by the surface concentration of thiols.

Effect of Variation in Ionic Strength ........................ D . Effect of Variation in Bulk Thiol Concentration .............. E. Significance for Studies with Enzymes ...................... F. Redox Indicators ......................................... G. Other Surface SH Problems ............................... IV. Partition of Reactants between Surface and Bulk Phases ........... V . Factors Influencing Rate of an Interfacial Reaction ................ A. Pressure, Temperature, and Tightness of Packing of Molecules or Ions in the Interface .................................

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